CP 2 TiCl 2 -catalyzed hydroalumination of internal alkynes: an access to ( Z )-olefins

Generation and reactions of low-valent titanium alkoxide-acetylene complexes. A practical preparation of allyl alcohols

Kousuke Harada, Hirokazu Urabe, Fumie Sato · Tetrahedron Letters · 1995 · 142 citations

Chemical Engineering, Cross-coupling Reaction, Allyl Alcohols +7

The preparation of Grignard reagents via the hydromagnesation reaction and their uses in organic synthesis

Fumie Sato · Journal of Organometallic Chemistry · 1985 · 113 citations

Chemical Engineering, Engineering, Grignard Reagents +7

Selective reduction of alkenes and alkynes by the reagent lithium aluminum hydride-transition-metal halide

E. C. Ashby, Jiang‐Jen Lin · The Journal of Organic Chemistry · 1978 · 93 citations · Full text

Materials Science, Chemical Engineering, Engineering +12

Selective reduction of alkynes to cis-alkenes by hydrometallation using [(Ph3P)CuH]6.

John F. Daeuble, Colleen McGettigan, Jeffrey M. Stryker · Tetrahedron Letters · 1990 · 92 citations

Chemical Engineering, Cross-coupling Reaction, Engineering +6

Stereo- and Regioselective Generation of Alkenylzinc Reagents via Titanium-Catalyzed Hydrozincation of Internal Acetylenes

Yuan Gao, Kousuke Harada, Takeshi Hata et al. · The Journal of Organic Chemistry · 1995 · 75 citations

Chemical Engineering, Internal Acetylenes, Titanium-catalyzed Hydrozincation +14