Concepedia

Variable Coordination Geometries in Manganese(II): Eight-, Seven-, and Six-Coordinate Mn(II) Complexes with Pyridyl-Containing Schiff-Base Ligands

Masahiro Mikuriya, Yasushi HATANO, Eiji Asato

Chemistry Letters · 1996 · 13 citations · 4 references

DOI

Concepts

Abstract

Abstract Eight, seven-, and six-coordinate manganese(II) complexes with N,N′-bis(2-pyridinylmethylene)-1,3-diaminopropan-2-ol(HL) and N,N′-bis(2-pyridinylmethylene)-1,3-diaminopropane(L′), [Mn(HL)(NO3)2]·C2H5OH, [Mn(L′)(NO3)2], [Mn(L′)(bipy)(CH3OH)](ClO4)2, [Mn(L′)(phen)](ClO4)2, and [MN2(L)(CH3COO)(phen)2](ClO4)2·H2O, have been isolated and characterized by X-ray crystallography.

References

4

Stereochemistry of Ethylenediamine tetraacetato Complexes. I. The Structure of Crystalline Mn<sub>3</sub>(HY)<sub>2</sub>.10H<sub>2</sub>O and the Configuration of the Seven-Coordinate Mn(OH<sub>2</sub>)Y<sup>-2</sup> Ion

S.N. Richards, Berit F. Pedersen, J. V. Silverton et al. · Inorganic Chemistry · 1964 · 135 citations

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Mononuclear Iron(II), Manganese(II), and Nickel(II) and Tetranuclear Iron(III) Complexes of a New Hexadentate Ligand

Navamoney Arulsamy, Joergen Glerup, Derek J. Hodgson · Inorganic Chemistry · 1994 · 47 citations

, , +9

Synthesis and Characterization of Mononuclear (Mn(II) and Mn(III)) and Dinuclear (Mn(II)Mn(II) and Mn(II)Mn(III)) Complexes with 2,6-Bis[<i>N</i>-(2-pyridylethyl)iminomethyl]-4-methylphenol

Masahiro Mikuriya, Toshinori Fujii, Tadashi Tokii et al. · Bulletin of the Chemical Society of Japan · 1993 · 44 citations

, , +17

Transition Metal in a Cube—A Discrete Eight‐Coordinate [Mn<sup>2+</sup> ⊂ [2.2.2]cryptand] as a Body Centered Cube with an N<sub>2</sub>O<sub>6</sub> Donor Set

Karl S. Hagen · Angewandte Chemie International Edition in English · 1992 · 33 citations

, , +15