AIChE Journal · 1971 · 63 citations · 6 references
EngineeringChemical EngineeringChemistryInterface SciencePhysical ChemistrySurface ChemistryAdsorption At InterfacesAdsorption ProcessesAdsorptive SeparationsPhase EquilibriaSolid-liquid InterfacesSurface AdsorptionAdsorption IsothermsAdsorption ThermodynamicsBinary MixturesGibbs AdsorptionGibbs EntropySurface Adsorption ThermodynamicsThermodynamic ConsistencyThermodynamic Consistency Testing
Abstract A thermodynamic consistency test for adsorption from binary liquid mixtures is derived using the Gibbs equation for adsorption. Adsorption data for the liquid mixture pairs A ‐ B , A ‐ C , and B ‐ C on the same adsorbent must be thermodynamically consistent. The consistency test is applied to experimental data for adsorption from the binary liquid mixtures benzene‐cyclohexane, benzene‐ n ‐heptane and cyclohexane‐ n ‐heptane on silica gel at 30°C.
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Thermodynamics of mixed‐gas adsorption
Alan L. Myers, John M. Prausnitz · AIChE Journal · 1965 · 3.7K citations
A.F. Forziati, Augustus R. Glasgow, Charles B. Willingham et al. · Journal of research of the National Bureau of Standards · 1946 · 81 citations · Full text