Organic & Biomolecular Chemistry · 2014 · 81 citations · 32 references
Natural SciencesChemistryMedicinal ChemistryCatalysisOrganic ChemistrySynthetic Medicinal ChemistryCatalytic MaterialsCross-coupling ReactionsHeterocycle SynthesisHeterocyclic ChemistryHeterocyclic CompoundsOrganic SynthesisC - H Bond FunctionalizationCarbazole ChemistryCarbazole SynthesisHeterocycle FunctionalizationIndole ChemistryIndole DerivativesIndole SynthesisRing-forming Reactions
Palladium(II)-catalyzed dual C-H functionalization of indoles with cyclic diaryliodoniums was successfully achieved, providing a concise method to synthesize dibenzocarbazoles. In a single operation, two C-C bonds and one ring were formed. The reaction was ligand free and tolerated air and moisture conditions.
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The Catalytic Cross-Coupling of Unactivated Arenes
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