Concepedia

Copper(I)-Catalyzed Carboxylation of Aryl- and Alkenylboronic Esters

Jun Takaya, Satoshi Tadami, Kazutoshi Ukai, Nobuharu Iwasawa

Organic Letters · 2008 · 255 citations · 42 references

DOI

Concepts

Abstract

The copper(I)-catalyzed carboxylation reaction of aryl- and alkenylboronic esters proceeded smoothly under CO(2) to give the corresponding carboxylic acid in good yield. This reaction showed wide generality with higher functional group tolerance compared to the corresponding Rh(I)-catalyzed reaction.

References

42

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