Simultaneous Dual Living Polymerizations: A Novel One-Step Approach to Block and Graft Copolymers

David Mecerreyes, G. Moineau, Philippe Dúbois, James L. Hedrick, Craig J. Hawker, Eva Malmström

Angewandte Chemie International Edition · 1998 · 214 citations · 0 references

Concepts

Abstract

Just one step is required for the synthesis of block copolymers by simultaneous "living"/controlled ring-opening and radical polymerization initiated by a difunctional (A-B) compound (shown schematically on the right).