Concepedia

Hydride Abstraction from η<sup>3</sup>-Allylic Molybdenum Complexes Exploring Various Diaryl Carbenium Ion Precursors. A Study toward Enantioselective Hydride Abstraction

Emelie Bjurling, Ulf Berg, Carl‐Magnus Andersson

Organometallics · 2002 · 10 citations · 13 references

DOI

Concepts

Abstract

The efficiency of trityl bromide ( 4 ) and diaryl carbenium ion precursors 5 − 7 in hydride abstraction from a series of cyclohexenyl molybdenum complexes ( 2 ) was investigated. The novel nonracemic hydride abstractors 14a, b were designed and prepared and were shown to effectuate hydride abstraction from prochiral substrate 15 with modest enantioselectivity.

References

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