Lab on a Chip · 2008 · 94 citations · 16 references
Natural SciencesChemical EngineeringMaterials ScienceCatalysisSurface ScienceThin FilmsCatalyst CharacterizationCatalyst DesignCatalyst SynthesisCatalytic Reaction EngineeringSupported CatalystsSurface CatalysisCatalyst ActivityCatalyst SelectivityCoating ThicknessCoating Thickness ControlHydrogenationHydrogenation ReactionsMesoporous MaterialsMicroreactors
A new method for catalyst deposition on the inner walls of capillary microreactors is proposed which allows exact control of the coating thickness, pore size of the support, metal particle size, and metal loading. The wall-coated microreactors have been tested in a selective hydrogenation reaction. Activity and selectivity reach values close to those obtained with a homogeneous Pd catalyst. The catalyst activity was stable for a period of 1000 h time-on-stream.
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Eduardo L. Crepaldi, Galo J. A. A. Soler‐Illia, David Grosso et al. · Journal of the American Chemical Society · 2003 · 896 citations
Hyunjoon Song, Robert M. Rioux, James D. Hoefelmeyer et al. · Journal of the American Chemical Society · 2006 · 517 citations