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Preparation and structure of a stable molecule containing a silicon nitrogen double bond and of its tetrahydrofuran adduct

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1986

Year

Abstract

The pale yellow, solid silaketimine But2N–SiBut3 has been prepared and structurally characterized [SiN 1.568(3)Å, Si–N–Si 177.8(2)°]; it forms a stable adduct with tetrahydrofuran by complexation of the unsaturated silicon atom.