Bulletin of the Chemical Society of Japan · 1988 · 37 citations · 10 references
Natural SciencesChemistryCatalysisOrganic ChemistryOrganometallic ChemistryCatalyst DesignCatalyst PreparationCatalyst SynthesisCatalytic MaterialsCatalyst Precursor DesignHydrogenationHydrogenation CatalysisHydrogenation ReactionsRuthenium-catalyzed CouplingSelectivity
Abstract The title compound was prepared and hydrogenated by using a Ru(II)- or Rh(I)-phosphine catalyst precursor with excellent anti-selectivity, the results indicating that a ligating group, NHCO2Me, may direct the addition of hydrogen to an olefinic diastereoface proximate to this group which binds the catalyst.
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