International Journal of Chemical Kinetics · 2001 · 148 citations · 39 references
EngineeringDifferential Scanning CalorimetryEnergy ConversionExperimental ThermodynamicsChemistryChemical EngineeringDerivative ThermogravimetryKinetics (Physics)ThermodynamicsReaction ProcessThermoanalytical MethodMaterials ScienceMethodological ProblemsKinetic ParametersEnergyThermal EngineeringReaction EngineeringThermal HydraulicsHeterogeneous Solid–gas ReactionsTransformation KineticsNonisothermal Kinetic AnalysisChemical KineticsThermal DegradationAbstract Isoconversional MethodsHydrothermal Processing
Abstract Isoconversional methods, those using only one curve α = α(T) (α is the conversion degree and T is the temperature), and invariant kinetic parameter method were applied to estimate the kinetic parameters from the following nonisothermal data: (1) simulated TG curves for a single reaction; (2) TG curves for thermal degradation of PVC; and (3) TG curves for the dehydration of CaC 2 O 4 ·H 2 O. The results obtained by applying various methods for the same system are compared and discussed. Finally, a procedure of kinetic analysis is suggested. Its application could lead to kinetic parameter values that can be used to predict either α = α(t) curves for other heating rates or α = α(T) curves for isothermal conditions. © 2001 John Wiley & Sons, Inc. Int J chem Kinet 33: 564–573, 2001
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Reaction Kinetics in Differential Thermal Analysis
H.E. Kissinger · Analytical Chemistry · 1957 · 12.9K citations
Engineering, E. Kissingercite, Altmetric Attention Score +20
Kinetic Parameters from Thermogravimetric Data
A. W. Coats, J. P. Redfern · Nature · 1964 · 6.7K citations
Engineering, Derivative Thermogravimetry, Numerical Simulation +7