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Giant reversible magnetocaloric effect in ErMn2Si2 compound with a second order magnetic phase transition
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Citations
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2012
Year
Magnetic PropertiesEngineeringMagnetic ResonanceChemistryMagnetic Entropy ChangeMagnetic MaterialsMagnetismGiant Reversible MceMagnetic RefrigerationThermodynamicsMaterials ScienceMagnetic MaterialTransition Metal ChalcogenidesFerromagnetismNatural SciencesApplied PhysicsCondensed Matter PhysicsErmn2si2 CompoundMagnetic Property
The magnetic properties and magnetocaloric effect (MCE) in the ternary intermetallic compound ErMn2Si2 have been studied by magnetization and heat capacity measurements. A giant reversible MCE has been observed, accompanied by a second order magnetic phase transition from paramagnetic to ferromagnetic at ∼4.5 K. Under a field change of 5 T, the maximum value of magnetic entropy change (−ΔSMmax) is 25.2 J kg−1 K−1 with no thermal and field hysteresis loss, and the corresponding maximum value of adiabatic temperature change (ΔTadmax) is 12.9 K. Particularly, the values of −ΔSMmax and ΔTadmax reached 20.0 J kg−1 K−1 and 5.4 K for a low field change of 2 T, respectively. The present results indicate that the ErMn2Si2 compound is an attractive candidate for low temperature magnetic refrigeration.
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