Application of Host−Guest Chemistry in Nanotube-Based Device Fabrication:  Photochemically Controlled Immobilization of Azobenzene Nanotubes on Patterned α-CD Monolayer/Au Substrates via Molecular Recognition

Abstract

Azobenzene-functionalized nanotubes recognized and attached onto well-defined complementary regions of thiolated alpha-CD SAM/Au substrates via host-guest molecular recognition. The binding between the azobenzene nanotubes and the alpha-CD SAM/Au substrates was controlled by UV irradiation. The light-induced attachment-detachment of the azobenzene nanotubes on the alpha-CD SAMs was reversible. Some of the nanotubes were capable of interconnecting two Au substrates. This smart building block may be applied to build photoactive nanometer-sized mechanical switches in electronics.