Concepedia

Phosphaalkene vs. phosphinidene: the nature of the P–C bond in carbonyl-decorated carbene → PPh adducts

Roberta R. Rodrigues, Christopher L. Dorsey, Chelsee A. Arceneaux, Todd W. Hudnall

Chemical Communications · 2013 · 102 citations · 53 references

DOI

Concepts

Abstract

Treatment of dichlorophenylphosphine with two equivalents of carbonyl-decorated carbenes results in a two-electron reduction of the phosphorus centre concomitant with carbene oxidation to afford novel phosphaalkenes as confirmed via crystallographic, spectroscopic, and DFT analyses.

References

53

Multiple Bonds and Low Coordination in Phosphorus Chemistry

John F. Nixon · Journal of Organometallic Chemistry · 1991 · 914 citations

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<sup>31</sup>P NMR Chemical Shifts of Carbene–Phosphinidene Adducts as an Indicator of the π‐Accepting Properties of Carbenes

O. Back, M. Henry-Ellinger, Caleb D. Martin et al. · Angewandte Chemie International Edition · 2013 · 491 citations

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Phosphaalkene, phospholyl and phosphinine ligands: New tools in coordination chemistry and catalysis

P. Le Floch · Coordination Chemistry Reviews · 2005 · 441 citations · Full text

, , +7

An <i>N</i>,<i>N</i>′-Diamidocarbene: Studies in C−H Insertion, Reversible Carbonylation, and Transition-Metal Coordination Chemistry

Todd W. Hudnall, Christopher W. Bielawski · Journal of the American Chemical Society · 2009 · 321 citations

, , +13

Nonmetal‐Mediated Fragmentation of P<sub>4</sub>: Isolation of P<sub>1</sub> and P<sub>2</sub> Bis(carbene) Adducts

O. Back, G. Kuchenbeiser, B. Donnadieu et al. · Angewandte Chemie International Edition · 2009 · 309 citations

, , +13