Journal of Applied Polymer Science · 1990 · 41 citations · 20 references
Natural SciencesChemistryMaterials SciencePolymer ChemistryThermal AnalysisThermodynamicsCalorimetryCatalytic Reaction KineticsChemical Kinetics ModelingKinetic ModelingPolymerization KineticsThermogravimetric AnalysisCuring KineticsEpoxy CuringEpoxy ResinsPhenomenological DescriptionPhenomenological Interpretation
Abstract The cure reaction of an epoxy‐novolac molding compound was studied by means of differential scanning calorimetry using the dynamic (i.e., temperature scanning) approach. Based on a modified version of Friedman's method, a procedure aiming at the phenomenological description of cure kinetics was developed. This method was found capable of following satisfactorily the thermokinetics of the molding compound. Our results indicate that the cure reaction is autocatalytic in nature and does not follow simple n th‐order kinetics.
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A New Analysis of Thermogravimetric Traces.
H. H. Horowitz, G. Metzger · Analytical Chemistry · 1963 · 2.3K citations