Langmuir · 2003 · 106 citations · 17 references
Natural SciencesPhysicsColloid ScienceCondensed Matter PhysicsOpticsColloidal Self-assemblyDefectsDefects In Electronic MaterialsOptical Properties Of SolidsSemiconductor DefectsBand GapConductionConduction BandDefect PhysicsDefect StatesDefects In Colloidal CrystalsOptical Band GapOptical Properties
A planar microcavity has been inserted into a self-assembled colloidal crystal by a combination of convective self-assembly in a vertical geometry and the Langmuir−Blodgett technique. This planar cavity, which is parallel to the {111} planes, induces the appearance of a localized state, a pass band, into the forbidden band gap. We have experimentally determined the optical properties of this defect. The dependence of the position of the localized state is investigated as a function of the thickness of the defect layer. It is found that the defect behaves as a donor impurity, as it originates in the conduction band. Analogously, the crystal surrounding a constant defect layer can be varied. It is also found that the pass band depends on the thickness of the surrounding crystal of the planar defect.
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Single-Crystal Colloidal Multilayers of Controlled Thickness
Peng Jiang, Jane F. Bertone, Kao‐Shing Hwang et al. · Chemistry of Materials · 1999 · 2K citations
Natural Sciences, Materials Engineering, Materials Science +17
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Judith E. G. J. Wijnhoven, Willem L. Vos · Science · 1998 · 1.6K citations