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Monomeric, Two-Coordinate, Univalent Chromium(I) Compounds: Steric Prevention of Metal−Metal Bond Formation
68
Citations
7
References
2007
Year
Materials ScienceInorganic ChemistryUnivalent ChromiumCr−cr Bond FormationEngineeringCoordination ComplexSteric PreventionBulky Terphenyl LigandMolecular ComplexAryl ChromiumChemistryMetal−metal Bond FormationInorganic SynthesisBiomolecular EngineeringInorganic Compound
Monomeric, two-coordinate, univalent, aryl chromium(I) species [(3,5-iPr2−Ar*)Cr(L)] (L = THF, PMe3) have been synthesized with use of a very bulky terphenyl ligand which prevents Cr−Cr bond formation.
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