Concepedia

A new binuclear ruthenium complex with an annelated C7 bridge via an unprecedented [2 + 2] coupling reaction

Stéphane Rigaut, Luc Le Pichon, Daniel Touchard, Pierre H. Dixneuf, Jean‐Claude Daran

Chemical Communications · 2001 · 41 citations · 15 references

DOI

Concepts

Abstract

Treatment of [Cl(dppe)2Ru–CC–CC–SiMe3 ] with [Fe(C5H5)2]PF6 leads to an unprecedented metal-assisted [2 + 2] coupling reaction on CγCδ bonds to obtain [Cl(dppe)2Ru–CC–CCHC(CH2 )CCRu(dppe)2Cl]PF6 with the charge highly delocalized over seven carbon atoms and including a cyclobutenyl bridge; the crystal structure was solved.

References

15

Toward Metal-Capped One-Dimensional Carbon Allotropes:  Wirelike C<sub>6</sub>−C<sub>20</sub>Polyynediyl Chains That Span Two Redox-Active (η<sup>5</sup>-C<sub>5</sub>Me<sub>5</sub>)Re(NO)(PPh<sub>3</sub>) Endgroups

Roman Dembiński, Tamás Bartik, Berit Bartik et al. · Journal of the American Chemical Society · 2000 · 406 citations

, , +7

Organometallic Complexes for Nonlinear Optics. 16.<sup>1</sup> Second and Third Order Optical Nonlinearities of Octopolar Alkynylruthenium Complexes

Andrew M. McDonagh, Mark G. Humphrey, Marek Samoć et al. · Journal of the American Chemical Society · 1999 · 175 citations

, , +14

New Forms of Coordinated Carbon:  Wirelike Cumulenic C<sub>3</sub> and C<sub>5</sub> sp Carbon Chains that Span Two Different Transition Metals and Mediate Charge Transfer

Tamás Bartik, Weiqing Weng, James A. Ramsden et al. · Journal of the American Chemical Society · 1998 · 114 citations

, , +15

Novel Ruthenium Allenylidene and Mixed Alkynyl Allenylidene Complexes:  Crystal Structure of <i>trans</i>-[(Ph<sub>2</sub>PCH<sub>2</sub>CH<sub>2</sub>PPh<sub>2</sub>)<sub>2</sub>Ru(C⋮CPh)(CCCPh<sub>2</sub>)]PF<sub>6</sub>

Daniel Touchard, Pierre Haquette, Alain Daridor et al. · Organometallics · 1998 · 72 citations

, , +11

Synthesis and characterisation of mono-acetylide and unsymmetrical bis-acetylide complexes of ruthenium and osmium: X-ray structure determinations on [(dppe)2Ru(Cl)(CC–C6H4-p-NO2)], [(dppe)2Ru(Cl)(CC–C6H3-o-CH3-p-NO2)] and [(dppm)2Os(CC–C6H4-p-CH3)(CC–C6H4-p-NO2)]

Muhammad Younus, Nicholas J. Long, Paul R. Raithby et al. · Journal of Organometallic Chemistry · 1999 · 59 citations

, , +17