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REACTIONS OF A STABLE THIOBENZALDEHYDE WITH ORGANOMETALLICS
10
Citations
7
References
1984
Year
Thioketyl RadicalsEngineeringRadical (Chemistry)Anion RadicalOrganic ChemistryAbstract ReactionsChemistryHeterocycle ChemistryAsymmetric CatalysisSynthetic ChemistryEnantioselective SynthesisBiomolecular Engineering
Abstract Reactions of 2,4,6-tri-t-butylthiobenzaldehyde with Grignard and organolithium reagents gave products via the anion radical of the thioaldehyde. The first example of dimerization of thioketyl radicals was also presented.
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