Concepedia

REACTIONS OF A STABLE THIOBENZALDEHYDE WITH ORGANOMETALLICS

Renji Okazaki, Nobuo Fukuda, Hiroyuki Oyama, Naoki Inamoto

Chemistry Letters · 1984 · 10 citations · 7 references

DOI

Concepts

Abstract

Abstract Reactions of 2,4,6-tri-t-butylthiobenzaldehyde with Grignard and organolithium reagents gave products via the anion radical of the thioaldehyde. The first example of dimerization of thioketyl radicals was also presented.

References

7

Thiophilic additions of organometallics to thiobenzophenones and of phenyllithium to phenyl dithiobenzoate and phenyl trithiocarbonate

Peter Beak, Jimmy W. Worley · Journal of the American Chemical Society · 1972 · 115 citations

, , +5

Addition reactions of some simple thioaldehydes

Jack E. Baldwin, Raḿon López · Tetrahedron · 1983 · 91 citations

, , +8

Heterophilic additions to carbonyls and thiocarbonyls. Scope and stereochemistry

Peter Beak, Jiro Yamamoto, Charles J. Upton · The Journal of Organic Chemistry · 1975 · 69 citations

, , +6

2,2-Dimethylpropanethial: a long-lived aliphatic thioaldehyde

Edwin Vedējs, David A. Perry · Journal of the American Chemical Society · 1983 · 56 citations

, , +6

Charge-transfer Intermediate in The Reaction of Thioketone with Nucleophiles

Atsuyoshi Ohno, Kaoru Nakamura, Misao Uohama et al. · Bulletin of the Chemical Society of Japan · 1975 · 54 citations

, , +7