Zeitschrift für Naturforschung B · 1994 · 19 citations · 0 references
Natural SciencesBiochemistryChemistryOrganic ChemistryOrganometallic ChemistrySynthetic Medicinal ChemistryCoordination ChemistryHeterocyclic ChemistryLigand BindingMetal-ligand BondingOrganometallic SynthesisTemplate SynthesisTemplate-assisted SynthesisX-ray Diffraction Analysis
(η5-C 5 Me 5 ) (M - Co, Rh, Ir) and (η5-p-cymene)(CI) have been obtained by reactions of (η5-C 5 Me 5 )Co(CO)I 2 , [(η 5 -C 5 Me 5 )MCl 2 ] 2 (M = Rh, Ir) and [(η 6 -p-cymene)RuCl 2 ] 2 with 2-hydroxyiminocarboxylates. These complexes are also accessible by template synthesis from hydroxylamine or O-methylhydroxylamine, α-oxocarboxylate and (η 5 -C 5 Me 5 )Co(CO)I 2 or [(η 5 -C 5 Me 5 )MCl 2 ] 2 (M = Rh, Ir). The structure of the S Ru enantiomer of (η 5 -C 5 Me 5 )(I) has been determined by X-ray diffraction.