Irradiation effects in carbon nanostructures

TLDR

In situ observation of dynamic processes at the atomic scale is crucial for studying irradiation effects in carbon nanostructures. The review examines how energetic particles interact with solid carbon and its nanostructures. It covers atom displacement mechanisms, defect formation and migration, ordering under irradiation, and electron‑beam effects on carbon nanostructures, especially graphite. Experimental evidence shows irradiation can create defects in fullerenes, nanotubes, and onions, and can drive self‑assembly of spherical onions and transform graphitic nanoparticles into diamond.

Abstract

The paper reviews the principles of interaction of energetic particles with solid carbon and carbon nanostructures. The reader is first introduced to the basic mechanisms of radiation effects in solids with particular emphasis on atom displacements by knock-on collisions. The influence of various parameters on the displacement cross sections of carbon atoms is discussed. The types of irradiation-induced defects and their migration are described as well as ordering phenomena which are observable under the non-equilibrium conditions of irradiation. The main part of this review deals with alterations of carbon nanostructures by the electron beam in an electron microscope. This type of experiment is of paramount importance because it allows in situ observation of dynamic processes on an atomic scale. In the second part, radiation effects in the modifications of elemental carbon, in particular in graphite which forms the crystallographic basis of most carbon nanostructures, are treated in detail. It follows a review of the available experimental results on radiation defects in carbon nanostructures such as fullerenes, nanotubes and carbon onions. Finally, the phenomena of structure formation under irradiation, in particular the self-assembling of spherical carbon onions and the irradiation-induced transformation of graphitic nanoparticles into diamond, are presented and discussed qualitatively in the context of non-equilibrium structure formation.