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VAPOR-PHASE BECKMANN REARRANGEMENT OF CYCLOHEXANONE OXIME OVER BORIA-HYDROXYAPATITE CATALYST
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1983
Year
Materials ScienceInorganic ChemistryBoron TrioxideEngineeringOrganic ChemistryCalcium AluminateCatalysisChemistryCatalyst PreparationBeckmann RearrangementCyclohexanone OximeCatalytic SynthesisBorophene
Abstract The boron trioxide coupled with hydroxyapatite was found to catalyze the Beckmann rearrangement of cyclohexanone oxime in the vapor phase at 300 °C more selectively than boria-alumina and silica-alumina. The basic property of hydroxyapatite appears to play an important role in effecting the rearrangement selectively.
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