Concepedia

C2-symmetric bis(oxazolinato) complexes of yttrium and lanthanum † ‡

H.W. Görlitzer, M. Spiegler, Reiner Anwander

Journal of the Chemical Society Dalton Transactions · 1999 · 43 citations · 8 references

DOI

Concepts

Abstract

Chiral 2,2′-methylene-bis[(4S)-4-tert-butyl-2-oxazoline] reacts with Ln[N(SiHMe2)2]3(thf)2 (Ln = Y, La) via an extended silylamide route to yield the first mono- and bis-(bisoxazolinato) complexes, potentially relevant to enantioselective catalysis.

References

8

Chiral semicorrins and related nitrogen heterocycles as ligands in asymmetric catalysis

Andreas Pfaltz · Accounts of Chemical Research · 1993 · 634 citations

, , +8

<i>C</i><sub>2</sub>‐Symmetric 4,4′,5,5′‐Tetrahydrobi(oxazoles) and 4,4′,5,5′‐Tetrahydro‐2,2′‐methylenebis[oxazoles] as Chiral Ligands for Enantioselective Catalysis Preliminary Communication

Dieter G. Müller, Gisela Umbricht, Beat Weber et al. · Helvetica Chimica Acta · 1991 · 459 citations

, , +10

Bis(trimethylsilyl)benzamidinate: a promising spectator ligand in organoyttrium chemistry. Synthesis and reactivity of {[C6H5C(NSiMe3)2]2Y-.mu.-R}2 (R = H, C.tplbond.CH) and x-ray structure of {[C6H5C(NSiMe3)2]2Y-.mu.-C.tplbond.CH}2

Robbert Duchateau, Cornelis T. van Wee, Auke Meetsma et al. · Journal of the American Chemical Society · 1993 · 167 citations · Full text

, , +9

Synthesis of Dialkylscandium Complexes Supported by β-Diketiminato Ligands and Activation with Tris(pentafluorophenyl)borane

Lawrence W. M. Lee, Warren E. Piers, M.R.J. Elsegood et al. · Organometallics · 1999 · 160 citations

, , +7

Crystal structure of the praseodymium β-diketonate of 2,2,6,6-tetramethyl-3,5-heptanedione, Pr<sub>2</sub>(thd)<sub>6</sub>

Corinda Erasmus, Jan C. A. Boeyens · Acta Crystallographica Section B · 1970 · 136 citations

, , +12