Advanced Materials · 1996 · 184 citations · 5 references
Natural SciencesChemistryMaterials SciencePolymer ChemistryPolymer MaterialsSolid-state ChemistryLiquid Crystal MaterialsLiquid CrystalsPolymer CrystallinityPolymer Phase BehaviorSolid-liquid InterfacesDendrimersDendritic Polymer StructureDendritic Polymer SynthesisDendritic PolymersLiquid Crystal Phase BehaviorLiquid Crystal PolymersLiquid Crystalline Polymer ConformationLiquid Crystalline Polymers
The first dendritic liquid crystalline polymer (DLCP) , consisting of a flexible, second‐generation dendritic carbosilane scaffold substituted with 36 rid cyanobiphenyl groups (see Figure), has been prepared. The synthesis and characterization of the mesophase are reported as an initial approach to determining how the formation of liquid crystal phases is related to the mesogen density and the spacer length in DLCPs. magnified image
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Toward "Willowlike" Thermotropic Dendrimers
Virgil Percec, Peihwei Chu, Masaya Kawasumi · Macromolecules · 1994 · 213 citations
Carbosilane-Based Dendritic Polyols
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