Applied Physics Letters · 2002 · 56 citations · 17 references
Natural SciencesMaterials EngineeringMaterials ScienceOptical MaterialsOpticsPhotonicsOptical ModulationOptical ModulatorsOptical PolymersOptical Thin FilmsPhotonic MaterialsRefractive IndexAll-optical ModulationAll-optical ModulatorsDifferential Phase ShiftExtinctionExtinction RatioLight-induced Refractive Index ChangeMach-zehnder ModulatorsPhotochromic Polymers
An all-optical Mach–Zehnder modulator is demonstrated which is composed of a polymer waveguide doped with a photochromic dye in the core and a thick light blocking metal layer on it. The metal layer was opened on one arm of the Mach–Zehnder modulator, so that only one arm of the modulator could be irradiated by modulation light, thus allowing a differential phase shift. The optical modulator exhibited an extinction ratio of about −12 dB at a wavelength of 1.55 μm. A simple kinetic model developed to delineate the refractive index change in the dye-doped polymer film was applied to predict the evolution of the modulation characteristics.
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Large and Stable Refractive Index Change in Photochromic Hybrid Materials
John Biteau, Fréderic Chaput, Khalid Lahlil et al. · Chemistry of Materials · 1998 · 130 citations
A High Quantum Yield Diarylethene-Backbone Photochromic Polymer
Francesco Stellacci, Chiaro Bertarelli, F. Toscano et al. · Advanced Materials · 1999 · 121 citations