Concepedia

Mild and Efficient Deoxygenation of Sulfoxides with a WCl<sub>6</sub>/Indium System

Byung Woo Yoo, Min Chol Park, Min Suk Song

Synthetic Communications · 2007 · 21 citations · 23 references

Concepts

Inorganic ChemistryChemical EngineeringEngineeringOxidation ResistanceAbstract DialkylEfficient DeoxygenationOrganic ChemistryCorresponding SulfidesCatalysisStereoselective SynthesisChemistryDesulfurizationRedox ChemistryWcl6/in SystemDeoxygenationChemical KineticsSynthetic Chemistry

Abstract

Abstract Dialkyl, diaryl, and aryl alkyl sulfoxides can be rapidly converted to the corresponding sulfides with a WCl6/In system in excellent yields under mild conditions.

References

23

Organic syntheses using indium-mediated and catalyzed reactions in aqueous media

Chao‐Jun Li, Tak Hang Chan · Tetrahedron · 1999 · 519 citations

Chemical Engineering, Engineering, Sustainable Synthesis +6

Asymmetric Synthesis Using Nucleophilic Reagents Containing a Chiral Sulfoxide Group

Guy Solladié · Synthesis · 1981 · 370 citations

Engineering, Chiral Sulfoxide Group, Organic Chemistry +6

Indium- and gallium-mediated carbon–carbon bond-forming reactions in organic synthesis

Vijay Nair, Sindu Ros, C. N. Jayan et al. · Tetrahedron · 2004 · 224 citations

Novel Organocatalysts, Engineering, Organic Chemistry +2

Reduction of sulfoxides to thioethers

M. Madesclaire · Tetrahedron · 1988 · 201 citations

Organic Chemistry, Deoxygenation, Chemistry +1

Efficient Deoxygenation of Sulfoxides to Thioethers and Reductive Coupling of Sulfonyl Chlorides to Disulfides with Tungsten Hexachloride

Habib Firouzabadi, Babak Karimi · Synthesis · 1999 · 51 citations

Chemical Engineering, Sulfinate Salts, Engineering +12