Polymer Engineering and Science · 1982 · 72 citations · 7 references
EngineeringMechanical EngineeringFiber SpinningNumerical SimulationPolymer PhysicTransport PhenomenaRheologySteady‐state MeltThermodynamicsMaterials SciencePhysicsStress CrystallizationMelt SpinningPolymer MeltPolymer ScienceApplied PhysicsPolymer PropertyTransformation KineticsThermal EngineeringSpun Yarn Birefringence
Abstract A model of melt spinning has been developed for speeds above which the effects of gravity, inertia, and aerodynamic drag become significant. The model has as an upper bound the speed at which stress crystallization begins to occur on the spin line. For poly(ethylene terephthalate), these velocities are approximately 750 and 3500 meters/minute. The calculated temperature and velocity profiles are shown to agree with measured values. The stress at the freeze point is calculated and found to correlate well with the spun yarn birefringence which, in turn, is shown to predict uniquely the spun yarn physical properties on a “simple” spin line. The stress‐optical coefficient derived from the calculated stress at the freeze point and measured birefringence agrees well with the literature.
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