Promoting effects of La for improved oxygen reduction activity and high stability of Pt on Pt–La alloy electrodes

Abstract

The design of polymer electrolyte fuel cell electrocatalysts depends on two equally important fundamental principles: the optimization of electrocatalytic activities as well as the long-term stability under operating conditions (e.g., pH < 1 and E > 0.8 V). Pt-based alloys with transition metals (i.e., Pt–La) address both of these key issues. The oxygen reduction kinetics depends on the alloy composition which, in turn, is related to the d-band center position. The stability of the oxygen reduction reaction is predictable by correlation of the d-band fillings and vacancies of Pt–M (M = Ti, Fe, Zr and La).