Journal of the American Ceramic Society · 2004 · 23 citations · 11 references
Natural SciencesMaterials EngineeringMaterials ScienceInorganic ChemistryMaterials ChemistrySurface ScienceConductive MaterialsHybrid MaterialsInorganic MaterialsIon-conducting MaterialsIonic ConductivityIonic ConductorsConductive Hybrid MaterialsConductivityHybrid Porous MaterialsOrganic-inorganic Hybrid MaterialsPoresProton ConductivityThiol ChemistryThiol Functionalization
An organic–inorganic hybrid ionic conductive material was prepared through oxidation of thiol groups in a surface‐modified porous glass. Surface‐modified pores in the hybrid materials acted as permeation paths for protons. Proton conductivity of the hybrid material was 4.2 × 10 −2 S/cm at 120°C under 100% relative humidity. This hybrid material was thermally stable at high temperature (above 100°C) due to the temperature‐tolerant inorganic frameworks.
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Functionalized Monolayers on Ordered Mesoporous Supports
Xiaming Feng, G.E. Fryxell, L.-Q. Wang et al. · Science · 1997 · 1.6K citations