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HYDROSILYLATION OF 1,4-BIS(TRIMETHYLSILYL)-1,3-BUTADIYNE
46
Citations
9
References
1985
Year
High YieldsChemical EngineeringEngineeringAbstract HydrosilylationOrganic ChemistryOrganometallic CatalysisCatalysisChemistryHydrosilylation OfEnantioselective SynthesisCatalytic SynthesisRhodium Catalyst
Abstract Hydrosilylation of 1,4-bis(trimethylsily)-1,3-butadiyne with platinum and rhodium catalyst proceeded stepwise to give first 2-silyl-1,4-bis(trimethylsilyl)-1-buten-3-ynes and then 1,3-disilyl-1,4-bis(trimethylsilyl)-1,2-butadienes in high yields.
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