Self‐Assembly of Thirty‐Six Atom Clusters (Li₁₂S₆O₆N₁₂) Containing Diazasulfite Anions

Abstract

Depending on the type of substituent on the nitrogen atom, the two thirtysix atom clusters of main group elements formed on treating RNSO with LiNHtBu adopt different structures (R = t Bu, SiMe3). For instance, the compound depicted on the right can be described as an aggregate of three hexagonal prisms.