Concepedia

Synthesis and ligand substitution reactions of a homoleptic acetonitrile dipalladium(i) complex

Tetsuro Murahashi, Tomoki Nagai, Taketoshi Okuno, Teruo Matsutani, Hideo Kurosawa

Chemical Communications · 2000 · 111 citations · 20 references

DOI

Concepts

Abstract

The first homoleptic nitrile dipalladium(I) complex [Pd2(CH3CN)6][BF4]2 is prepared; the CH3CN ligand undergoes facile displacement by phosphine or bidentate nitrogen ligands while the Pd–Pd bond remains intact.

References

20

Catalysis by solvated transition-metal cations. Novel catalytic transformations of alkenes by tetrakis(acetonitrile)palladium ditetrafluoroborate. Evidence for the formation of incipient carbonium ions as intermediates

Ayusman Sen, Ta-Wang Lai · Journal of the American Chemical Society · 1981 · 137 citations

, , +15

A Remarkable Family of Rhodium Acetonitrile Compounds Spanning Three Oxidation States and with Nuclearities Ranging from Mononuclear and Dinuclear to One-Dimensional Chains

Matthew E. Prater, Laura E. Pence, Rodolphe Clérac et al. · Journal of the American Chemical Society · 1999 · 124 citations

, , +11

Organometallic Sandwich Chains Made of Conjugated Polyenes and Metal−Metal Chains

Tetsuro Murahashi, Eiko Mochizuki, Yasushi Kai et al. · Journal of the American Chemical Society · 1999 · 109 citations

, , +13

Organometallic chemistry of electrophilic transition and lanthanide metal ions. The dominant pathways for reactions involving carbon-carbon double and single bonds and carbon-hydrogen bonds

Ayusman Sen · Accounts of Chemical Research · 1988 · 102 citations

, , +8

Reactions of electrophilic transition metal cations with olefins and small ring compounds. Rearrangements and polymerizations

Ayusman Sen, Ta-Wang Lai, Richard R. Thomas · Journal of Organometallic Chemistry · 1988 · 99 citations

, , +7