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Synthetic and reactivity studies of mono- and dicyclopentadienyl titanium, zirconium and hafnium complexes with the chlorodimethylsilyl-cyclopentadienyl ligand. X-ray molecular structure of Hf{(η5-C5H4)SiMe2OSiMe2(η5-C5H4)}Cl2 and Zr(η5-1,3- Bu2C5H3)(η5-C5H4SiMe2-η-N Bu)Cl

Santiago Ciruelos, Alfredo Sebastián, Tomás Cuenca, Pilar Gómez‐Sal, Antonio Manzanero, Pascual Royo

Journal of Organometallic Chemistry · 2000 · 29 citations · 52 references

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52

Phase annealing in SHELX-90: direct methods for larger structures

George M. Sheldrick · Acta Crystallographica Section A Foundations of Crystallography · 1990 · 16.3K citations

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Stereospecific Olefin Polymerization with Chiral Metallocene Catalysts

Hans H. Brintzinger, David M. Fischer, Rolf Mülhaupt et al. · Angewandte Chemie International Edition in English · 1995 · 2.7K citations

, , +17

Scandium complex [{(.eta.5-C5Me4)Me2Si(.eta.1-NCMe3)}(PMe3)ScH]2: a unique example of a single-component .alpha.-olefin polymerization catalyst

Pamela J. Shapiro, Emilio E. Bunel, William P. Schaefer et al. · Organometallics · 1990 · 537 citations

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Homogeneous group 4 metallocene ziegler-natta catalysts: The influence of cyclopentadienyl-ring substituents

Petra C. Möhring, Neil J. Coville · Journal of Organometallic Chemistry · 1994 · 528 citations

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Model Ziegler-Natta .alpha.-Olefin Polymerization Catalysts Derived from[{(.eta.5-C5Me4)SiMe2(.eta.1-NCMe3)}(PMe3)Sc(.mu.2-H)]2 and[{(.eta.5-C5Me4)SiMe2(.eta.1-NCMe3)}Sc(.mu.2-CH2CH2CH3)]2. Synthesis, Structures, and Kinetic and Equilibrium Investigations of the Catalytically Active Species in Solution

Pamela J. Shapiro, William P. Schaefer, Jay A. Labinger et al. · Journal of the American Chemical Society · 1994 · 472 citations

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