Publication | Closed Access
First observation of a ferromagnetic interaction through an end-to-end azido bridging pathway in a 1D copper(ii) system
126
Citations
18
References
2001
Year
Magnetic PropertiesEngineeringMagnetic ResonanceChemistryMagnetoresistanceInorganic CompoundMagnetismFerromagnetic InteractionMaterials ScienceInorganic ChemistryPhysicsPhysical ChemistryEnd-to-end AzidoFirst ObservationInorganic SynthesisNovel One-dimensional CopperQuantum MagnetismSpintronicsFerromagnetismTransition Metal ChalcogenidesMolecule-based MagnetNatural SciencesCoordination ComplexApplied PhysicsDft CalculationMetal Chain Compound
A novel one-dimensional copper(II) compound [Cu(L)(μ1,3-N3)(ClO4)]n [L = tridentate Schiff base, formed by condensation of pyridine-2-aldehyde and 1-(2-aminoethyl)piperidine] has been synthesized and structurally characterized; it exhibits ferromagnetic interaction via end-to-end azido (μ1,3-N3) linkages, as rationalised by DFT calculation.
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