Organometallics · 1998 · 637 citations · 22 references
Natural SciencesChemical EngineeringChemistryCatalysisInorganic ChemistryPolymer ChemistryCatalyst DesignCatalyst SynthesisCatalytic MaterialsCoordination ChemistryOlefin PolymerizationPolymerization ChemistryMild Reaction ConditionsNickel CatalysisNickel CatalystsPhosphine ReactivityX-ray Spectral Analysis
Neutral salicylaldiminato Ni(II) complexes have been synthesized, and their structure has been confirmed by an X-ray analysis of complex 4e . These compounds are active catalysts for the polymerization of ethylene under mild conditions in the presence of a phosphine scavenger such as Ni(COD) 2 or B(C 6 F 5 ) 3 .
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Christopher M. Killian, Daniel J. Tempel, Lynda K. Johnson et al. · Journal of the American Chemical Society · 1996 · 880 citations