The stereochemistry of the biosynthetic precursor of gossypol

Robert D. Stipanovic, Albert Stoessl, J. B. Stothers, David W. Altman, Alois A. Bell, Peter Heinstein

Journal of the Chemical Society Chemical Communications · 1986 · 30 citations · 0 references

Concepts

Abstract

cis-trans-Farnesyl pyrophosphate or an equivalent such as nerolidyl pyrophosphate in contrast to earlier work, has been established, through [1,2-13C2]acetate feeding, as the main biosynthetic precursor of gossypol in chilled cotton (Gossypium arboreum) radicals.