Plasma Processes and Polymers · 2013 · 27 citations · 26 references
Natural SciencesMaterials EngineeringMaterials ScienceElectrochemical EngineeringElectrochemistrySurface ScienceBattery MaterialsElectrode MaterialsSeparator MaterialsElectrochemical MeasurementsLithium-ion Battery SeparatorsMembrane SeparatorsPolymer SeparatorsPolymer Surface ModificationRechargeable BatteriesSurface PropertiesWater Contact Angle
Abstract This paper reported surface modification and characterization of polymeric separators by cyclonic atmospheric‐pressure plasma for Li‐ion battery use. Water contact angles of the plasma‐modified polymeric separator decreased with increasing treatment time and plasma power. Variations in surface morphology and chemical structure of the plasma‐modified polymeric separators were confirmed by FESEM and XPS. XPS analysis revealed that the surfaces of plasma‐modified polymeric separators had significantly higher concentrations of oxygen functional groups. Moreover, the cyclonic atmospheric‐pressure plasma‐modified polymeric separators showed excellent performance in electrochemical measurements. magnified image
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Estimation of the surface free energy of polymers
D.K. Owens, R. C. Wendt · Journal of Applied Polymer Science · 1969 · 9.2K citations
Natural Sciences, Chemistry, Physics +17