Journal of Coordination Chemistry · 2015 · 11 citations · 22 references
Natural SciencesChemistryInorganic ChemistryMagnetic MaterialsOrganometallic ChemistryCoordination ChemistryMagnetic OxidesMagnetic SusceptibilityMagnetism Of Inorganic CompoundsCoordination Compound MagnetismMagnetic Properties Of Coordination ComplexesMagnetic Properties Of Transition Metal ComplexesMagnetic Susceptibility AnalysisMagnetism Of Transition Metal ComplexesManganese ChemistryMolecular Magnetism
The reaction between manganese nitrate and <i>N,Nʹ</i>-(±)-ethylene-bis(salicylicyclohexanediaminate) ((±)-salcy) in dilute lacunary polyoxoanion [PW<sub>9</sub>O<sub>34</sub>]<sup>9−</sup> solution led to isolation of a new Mn-dimer, [Mn((±)-salcy)(N<sub>3</sub>)]<sub>2</sub> (<b>1</b>). Structural analysis indicates that <b>1</b> represents the first salcy-based Mn-dimer complex. Magnetic susceptibility studies reveal that <b>1</b> shows single-molecule magnet (SMM) behavior from 2 to 5 K.
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A short history of<i>SHELX</i>
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