Concepedia

A novel α-acrylate anion equivalent: a useful synthon for α-substituted acrylic esters

Pier Giovanni Baraldi, A. BARCO, Simonetta Benetti, F Moroder, G. P. POLLINI, Daniele Simoni, Vinicio Zanirato

Journal of the Chemical Society Chemical Communications · 1982 · 12 citations · 0 references

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Abstract

An efficient preparation of a-substituted acrylic esters is described, based on Dieckmann-Michael retrograde reactions of the C-alkylation products of 4-methoxycarbonylthiolan-3-one