Concepedia

Olefin epoxidation with hydrogen peroxide using octamolybdate-based self-separating catalysts

Mingdong Zhou, Meiju Liu, Liangliang Huang, Jian Zhang, Jingyun Wang, Xuebing Li, Fritz E. Kühn, Shuliang Zang

Green Chemistry · 2014 · 50 citations · 41 references

DOI

Concepts

Abstract

Alkylimidazolium/alkylpyridinium octamolybdates can be used as self-separating catalysts in acetonitrile-mediated olefin epoxidations using hydrogen peroxide as oxidant.

References

41

Characterization and comparison of hydrophilic and hydrophobic room temperature ionic liquids incorporating the imidazolium cation

Jonathan G. Huddleston, Ann E. Visser, W.M. Reichert et al. · Green Chemistry · 2001 · 3.6K citations

, , +14

Novel Brønsted Acidic Ionic Liquids and Their Use as Dual Solvent−Catalysts

Amanda C. Cole, Jessica L. Jensen, Ioanna Ntai et al. · Journal of the American Chemical Society · 2002 · 1.2K citations

, , +16

Recent advances in ionic liquid catalysis

Qinghua Zhang, Shiguo Zhang, Youquan Deng · Green Chemistry · 2011 · 700 citations

, , +13

Epoxidation of olefins with hydrogen peroxide catalyzed by polyoxometalates

Noritaka Mizuno, Kazuya Yamaguchi, Keigo Kamata · Coordination Chemistry Reviews · 2005 · 670 citations

, , +3

Efficient Epoxidation of Olefins with ≥99% Selectivity and Use of Hydrogen Peroxide

Keigo Kamata, Koji Yonehara, Yasutaka Sumida et al. · Science · 2003 · 635 citations

, , +15