Concepedia

A novel allylic transfer reaction of chirally modified 2-borylbutadiene: synthesis of chiral homoallenyl alcohols

Ji‐Hoon Choi, Bobin Lee, Chan‐Mo Yu

Chemical Communications · 2011 · 19 citations · 35 references

DOI

Concepts

Abstract

An enantioselective synthesis of the homoallenyl alcohols was achieved from the reaction of chiral 2-borylbutadiene with aldehydes through an allylic transfer reaction in good yields and enantioselectivities.

References

35

Electrophilic Addition and Cyclization Reactions of Allenes

Shengming Ma · Accounts of Chemical Research · 2009 · 625 citations

, , +12

Diastereogenic Addition of Crotylmetal Compounds to Aldehydes

Reinhard W. Hoffmann · Angewandte Chemie International Edition in English · 1982 · 381 citations

, , +11

Enantiomeric Z- and E-crotyldiisopinocampheylboranes. Synthesis in high optical purity of all four possible stereoisomers of .beta.-methylhomoallyl alcohols

Herbert C. Brown, K. S. BHAT · Journal of the American Chemical Society · 1986 · 321 citations

, , +13

Diastereo- and enantioselective aldehyde addition reactions of 2-allyl-1,3,2-dioxaborolane-4,5-dicarboxylic esters, a useful class of tartrate ester modified allylboronates

William Roush, Alan E. Walts, Lee K. Hoong · Journal of the American Chemical Society · 1985 · 308 citations

, , +15

Catalytic enantioselective synthesis of axially chiral allenes

Masamichi Ogasawara · Tetrahedron Asymmetry · 2009 · 298 citations

, , +4