Concepedia

Palladium catalysed electrosynthesis using aryl trifluoromethanesulfonates (triflates). Synthesis of biaryls and aromatic carboxylic acids

Anny Jutand, Serge Négri, Adil Mosleh

Journal of the Chemical Society Chemical Communications · 1992 · 52 citations · 24 references

DOI

Concepts

Abstract

The palladium(II) complex [PdCl2(PPh3)2] catalyses the electrosynthesis of biaryls from aryl triflates whereas, in the presence of carbon dioxide, this complex catalyses the electrosynthesis of aromatic carboxylic acids.

References

24

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Role and effects of halide ions on the rates and mechanisms of oxidative addition of iodobenzene to low-ligated zerovalent palladium complexes Pd0(PPh3)2

Christian Amatore, Mohamed Azzabi, Anny Jutand · Journal of the American Chemical Society · 1991 · 281 citations

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Antonio M. Echavarren, J. K. Stille · Journal of the American Chemical Society · 1988 · 226 citations

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Nickel-phosphine complex-catalyzed homo coupling of aryl halides in the presence of zinc powder

Michio Zembayashi, Kohei Tamao, Jun‐ichi Yoshida et al. · Tetrahedron Letters · 1977 · 188 citations

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