CRYSTAL STRUCTURE OF (BMDT-TTF)3ClO4(1,2-DICHLOROETHANE). MOLECULAR DESIGN FOR THE MULTI-DIMENSIONAL MOLECULAR CONDUCTOR

Reìzo Kato, Hayao Kobayashi, Akiko Kobayashi, Yukiyoshi Sasaki

Chemistry Letters · 1984 · 18 citations · 3 references

Concepts

Abstract

Abstract In the crystal of (BMDT-TTF)3ClO4(1,2-dichloroethane), inclined BMDT-TTF (bis(methylenedithio)TTF) molecules with dihedral angles of 57–58° construct the two-dimensional S···S network parallel to the ac plane. The steric and electronic features of BMDT-TTF suggest that BMDT-TTF will take a wide variety of the molecular arrangement which lead to the multi-dimensional molecular conductors.

References

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