Concepedia

Rhenium-Catalyzed Hydroamidation of Unactivated Terminal Alkynes:  Synthesis of (<i>E</i>)-Enamides

Salprima Yudha S., Yoichiro Kuninobu, Kazuhiko Takai

Organic Letters · 2007 · 66 citations · 9 references

DOI

Concepts

Abstract

Reactions of cyclic amides with unactivated terminal alkynes in the presence of a catalytic amount of a rhenium complex provided (E)-enamides in high regio- and stereoselectivity (E:Z = >99:<1).

References

9

Rhenium-Catalyzed Formation of Indene Frameworks via C−H Bond Activation:  [3+2] Annulation of Aromatic Aldimines and Acetylenes

Yoichiro Kuninobu, Atsushi Kawata, Kazuhiko Takai · Journal of the American Chemical Society · 2005 · 253 citations

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Isomerization of N-allylamides and -imides to aliphatic enamides by iron, rhodium, and ruthenium complexes

J. K. Stille, Y. Becker · The Journal of Organic Chemistry · 1980 · 178 citations

, , +6

Ru‐Catalyzed Anti‐Markovnikov Addition of Amides to Alkynes: A Regio‐ and Stereoselective Synthesis of Enamides

Lukas J. Gooßen, Jan E. Rauhaus, Guo‐Jun Deng · Angewandte Chemie International Edition · 2005 · 133 citations · Full text

, , +11

Rhenium‐ and Aniline‐Catalyzed One‐Pot Annulation of Aromatic Ketones and α,β‐Unsaturated Esters Initiated by CH Bond Activation

Yoichiro Kuninobu, Yuta Nishina, Makoto Shouho et al. · Angewandte Chemie International Edition · 2006 · 128 citations

, , +8

Palladium(II)-catalyzed amidation of alkenes

Takahiro Hosokawa, M Takano, Yoshichika Kuroki et al. · Tetrahedron Letters · 1992 · 122 citations

, , +8