Concepedia

Free Radical Reactions of Stable Silylenes and Germylenes

Akinobu Naka, Nicholas J. Hill, Robert West

Organometallics · 2004 · 47 citations · 4 references

DOI

Concepts

Abstract

Compound 1 reacts with TEMPO to yield the disiloxane 5 as the major product. Stable germylenes 9 and 10 both reacted with TEMPO to yield the 1:2 adducts. The reaction of 1 with di- tert -butyl peroxide gave the 1:2 adduct 7 in addition to 15% of an unexpected trisilane, 8 .

References

4

The First Isolable Dialkylsilylene

Mitsuo Kira, Shintaro Ishida, Takeaki Iwamoto et al. · Journal of the American Chemical Society · 1999 · 441 citations

, , +4

Addition of Stable Nitroxide Radical to Stable Divalent Compounds of Heavier Group 14 Elements

Takeaki Iwamoto, Hidenori Masuda, Shintaro Ishida et al. · Journal of the American Chemical Society · 2003 · 100 citations

, , +8

Diverse reactions of nitroxide-radical adducts of silylene, germylene, and stannylene

Takeaki Iwamoto, Hidenori Masuda, Shintaro Ishida et al. · Journal of Organometallic Chemistry · 2004 · 59 citations

, , +5

Radical Reactions of a Stable N-Heterocyclic Silylene:  EPR Study and DFT Calculation

Boris Tumanskii, Pauline Pine, Yitzhak Apeloig et al. · Journal of the American Chemical Society · 2004 · 47 citations

, , +12