Concepedia

A novel system consisting of Rh–DuPHOS and ionic liquid for asymmetric hydrogenations

Silvina Guernik, Adi Wolfson, M. Herskowitz, Noam Greenspoon, Shimona Geresh

Chemical Communications · 2001 · 81 citations · 5 references

DOI

Concepts

Abstract

The ionic liquid [bmim][PF6] was found to provide extra stability to the air-sensitive chiral catalyst Rh-MeDuPHOS in asymmetric hydrogenation of enamides.

References

5

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Room-temperature ionic liquids as replacements for organic solvents in multiphase bioprocess operations

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Asymmetric Hydrogenation and Catalyst Recycling Using Ionic Liquid and Supercritical Carbon Dioxide

Richard A. Brown, Paméla Pollet, Erin P. McKoon et al. · Journal of the American Chemical Society · 2001 · 401 citations

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Design and synthesis of a heterogeneous asymmetric catalyst

Kam T. Wan, Mark E. Davis · Nature · 1994 · 235 citations

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Ionic liquid-phase asymmetric catalytic hydrogenation: hydrogen concentration effects on enantioselectivity

Alexsandro Berger, Roberto Fernando de Souza, Marcelo R. Delgado et al. · Tetrahedron Asymmetry · 2001 · 141 citations

, , +14