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Novel Ga<sub>2</sub>N<sub>2</sub> Ring Systems by Reaction of Pentamethylcyclopentadienylgallium with Organic Azides
40
Citations
5
References
1999
Year
Inorganic ChemistryChemical EngineeringDimeric IminogallaneEngineeringHeterocyclicOrganic AzidesOrganic ChemistrySolid-state StructuresMain Group ChemistryChemistryHeterocycle ChemistrySynthetic ChemistryBiomolecular Engineering
Two different types of compounds are observed in the kinetically controlled reaction of pentamethylcyclopentadienylgallium (Cp*Ga) (1) with organic azides: the dimeric iminogallane (η1-Cp*GaNXyl)2 (2) and the dimeric azide-bridged gallane [(η1-Cp*)Ga(μ2-N3){N(SiMe3)2}]2 (4). The solid-state structures of 2 and 4 are discussed.
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