Concepedia

Rhodium-Catalyzed Imination of Sulfoxides and Sulfides:  Efficient Preparation of N-Unsubstituted Sulfoximines and Sulfilimines

Hiroaki Okamura, Carsten Bolm

Organic Letters · 2004 · 187 citations · 11 references

DOI

Concepts

Abstract

The Rh(II)-catalyzed imination of sulfoxides and sulfides using [Rh(2)(OAc)(4)] as a catalyst and trifluoroacetamide or sulfonylamides in combination with iodobenzene diacetate and magnesium oxide affords sulfoximines and sulfilimines, respectively, in a stereospecific manner. [reaction: see text]

References

11

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Highly Enantioselective Hetero-Diels−Alder Reactions Catalyzed by a<i>C</i><sub>2</sub>-Symmetric Bis(sulfoximine) Copper(II) Complex

Carsten Bolm, Oliver Simić · Journal of the American Chemical Society · 2001 · 173 citations

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Synthesis and some properties of O-acyl-and O-nitrophenylhydroxylamines

Y. TAMURA, J. MINAMIKAWA, Kunihiro Sumoto et al. · The Journal of Organic Chemistry · 1973 · 161 citations

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Mn-salen catalyzed nitrene transfer reaction: Enantioselective imidation of alkyl aryl sulfides

Hisashi Nishikori, Chisa Ohta, Eva Oberlin et al. · Tetrahedron · 1999 · 77 citations

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Synthesis of Pseudopeptides with Sulfoximines as Chiral Backbone Modifying Elements

Carsten Bolm, Guido Moll, Jan D. Kahmann · Chemistry - A European Journal · 2001 · 60 citations

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