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Calcium-Catalyzed Intermolecular Hydrophosphination
206
Citations
23
References
2007
Year
Inorganic ChemistryEngineeringAlkene MetathesisEffects Intermolecular HydrophosphinationPhosphine-terminated MacromoleculesOrganometallic CatalysisCatalysisMolecular ComplexChemistryMolecular CatalysisAsymmetric CatalysisElectrophilic AlkeneCalcium-catalyzed Intermolecular HydrophosphinationBiomolecular Engineering
The β-diketiminato complex [{HC(C(Me)2N-2,6-iPr2C6H3)2}Ca{N(SiMe3)2}(THF)] effects intermolecular hydrophosphination of a range of alkenes and alkynes. In behavior reminiscent of lanthanocene(III) catalysis, a more electrophilic alkene is polymerized to phosphine-terminated macromolecules.
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