Noncovalent functionalization of multiwalled and double‐walled carbon nanotubes: Positive effect of the filler functionalization on high glass transition temperature epoxy resins

Abstract

Abstract Double‐walled carbon nanotubes (DWCNTs) and multiwalled carbon nanotubes (MWCNTs) were modified using melamine to attach NH 2 to the surface of these fillers, without previous oxidation of their graphene layers. FT‐Raman, elemental (chemical) and thermogravimetric analysis, confirmed the modification, which was more extensive for DWCNTs. The potential of this modification was evaluated by adding the melamin‐modified nanotubes to thermosets based on diglycidyl ether of bisphenol A (resin) and polycyclic amine (hardener). Broadening of the glass transition interval and an increase between 7 and 8 °C of the glass transition temperatures show better filler/matrix interaction for the nanocomposites based on melamine‐modified nanotubes. © 2009 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 47: 1860–1868, 2009